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Investigation of the Activity of a Molybdenum-Containing Catalyst in the Methane Aromatization Reaction

Fayzullaev Normurot IbodullaevichDoctor of Technical Sciences, Professor, Samarkand State University, Samarkand, UzbekistanSaginaev Amanjan TuremuratovichDoctor of Chemical Sciences, Professor, Head of the Department of Petrochemistry, Atyrau Oil and Gas University, Atyrau, KazakhstanXolliyev Shamsiddin XudoyberdiyvichDoctoral student, Department of polymer chemistry and Chemical Technology, Samarkand State University, Samarkand, UzbekistaQobilov Ergash cEgamberdievichDoctor of Medical Sciences, professor, Department of Ecology and life activity security, Samarkand State University, Samarkand, Uzbekistan
SSRN Electronic Journalrepository2020en
ABI

Аннотация

Molybdenum-containing catalysts have high catalytic activity in methane aromatization reaction without the participation of oxidizing agents. The effect of the ratio of active components on the activity and efficiency of the catalyst was studied and the possibility of achieving a high result when adding zirconium to the composition of the molybdenum-based catalyst was proved. As a result of the studies, a catalyst of the optimal composition of 5.0% Mo•1,0% Zr•1,0% Zn/bentonite was selected. The dependence of the rate of the methane aromatization reaction without an oxidizing agent, the yield and selectivity of aromatic hydrocarbons, as well as the conversion of starting materials from temperature, volume speed, contact time, the ratio of active catalyst components, was studied and the following optimal reaction conditions were chosen: T = 750 оC, the volume feed rate of methane 1000 h-1. Under optimal conditions, the yield of aromatic hydrocarbons is 40.4%

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