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A green chemistry approach for oxidation of alcohols using novel bioactive cobalt composite immobilized on polysulfone fibrous network nanoparticles as a catalyst

Andrés Alexis Ramírez‐CoronelLaboratory of Psychometrics, Comparative Psychology and Ethology (LABPPCE), Health and Behavior Research Group (HBR), Cuenca, EcuadorSalim Oudah MezanIndrajit PatraAn Independent Researcher, NIT Durgapur, Durgapur, West Bengal, IndiaR. SivaramanDepartment of Mathematics, Dwaraka Doss Goverdhan Doss Vaishnav College, University of Madras, Chennai, IndiaYassine RiadiDepartment of Pharmaceutical Chemistry, College of Pharmacy, Prince Sattam bin Abdulaziz University, Al-Kharj, Saudi ArabiaShukhrat KhakberdievHead of the Chemistry Department, Jizzakh Polytechnic Institute, Jizzakh, UzbekistanHolya A. LaftaAl-Nisour University College, Baghdad, IraqMunther AbosaoodaCollege of Pharmacy, The Islamic University, Najaf, IraqAbduladheem Turki JalilMedical Laboratories Techniques Department, Al-Mustaqbal University College, Hilla, Babylon, IraqYasser Fakri MustafaDepartment of Pharmaceutical Chemistry, College of Pharmacy, University of Mosul, Mosul, Iraq
Frontiers in Chemistryjournal2022en
ABI

Аннотация

In this study, cobalt composite immobilized on polysulfone fibrous network nanoparticles (CCPSF NPs) were synthesized in a controllable and one-step way under microwave - assisted conditions. The structure of CCPSF NPs was characterized by SEM images (for morphology and size distribution), TGA (for thermal stability), BET technique (for the specific surface area), FT-IR spectroscopy (for relation group characterization), and XRD patterns (for crystal size). The oxidation of the primary and secondary alcohols to aldehyde and ketone was investigated using synthesized CCPSF NPs under solvent-free microwave-assisted conditions, and high oxidizing activity was observed. In addition to oxidation properties, the anticancer activity of the synthesized CCPSF NPs in breast cancer was evaluated by the MTT method , and significant results were obtained.

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