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Enhanced Photocatalytic Performance of Cr/Ni/Mg/Al Layered Double Hydroxides against Methyl Orange in Aqueous Solution

Tayyaba WaheedState Key Laboratory of Chemical Resource Engineering, Beijing Engineering Center for Hierarchical Catalysts, Beijing University of Chemical Technology, No. 15 Beisanhuan East Road, Chaoyang District, Beijing 100029, ChinaMin PuState Key Laboratory of Chemical Resource Engineering, Beijing Engineering Center for Hierarchical Catalysts, Beijing University of Chemical Technology, No. 15 Beisanhuan East Road, Chaoyang District, Beijing 100029, ChinaShafia ShujaatDepartment of Chemistry, University of Azad Jammu and Kashmir, Muzaffarabad 13100, PakistanSirajul HaqDepartment of Chemistry, University of Azad Jammu and Kashmir, Muzaffarabad 13100, PakistanSalah Ud DinDepartment of Chemistry, University of Azad Jammu and Kashmir, Muzaffarabad 13100, PakistanM. Khalid HossainInstitute of Electronics, Atomic Energy Research Establishment, Bangladesh Atomic Energy Commission, Dhaka 1349, BangladeshFazal Ur RehmanDepartment of Chemistry, University of Azad Jammu and Kashmir, Muzaffarabad 13100, PakistanAsad SyedDepartment of Botany and Microbiology, College of Science, King Saud University, P.O. 2455, Riyadh 11451, Saudi ArabiaAli H. BahkaliDepartment of Botany and Microbiology, College of Science, King Saud University, P.O. 2455, Riyadh 11451, Saudi ArabiaLing Shing WongFaculty of Health and Life Sciences, INTI International University, Putra Nilai, 71800 Nilai, Negeri Sembilan, MalaysiaJamoliddin RazzokovDepartment of Biomedical Engineering, Tashkent State Technical University, Tashkent 100095, Uzbekistan
ABI

Аннотация

Layered double hydroxides (LDHs) have received substantial research as manufacturing innovation and prospective photocatalysts for the degradation of organic contaminants due to large surface area, strong anionic exchange capacity, and tunable composition. In this study, we modified Mg/Al-LDHs with Ni and Cr to further enhance their performance in removing Methyl Orange (MO) an anionic dye widely used in textiles, cosmetics, and healthcare products. The modified Mg/Al-LDHs were synthesized using hydrothermal co-precipitation method and characterized by Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), transmission electron microscope (TEM), and X-ray diffraction (XRD). The breakdown rate of MO under solar light was used for evaluating the material's photocatalytic activity. The outcomes demonstrated that the Ni/Mg/Al/Cr (LDH-4) photocatalysts degraded MO more quickly than the undoped substance. The addition of Cr to the Ni/Mg/Al matrix caused the band gap to develop new energy levels, which increased the material's photocatalytic activity. The Ni/Mg/Al doped with Cr has demonstrated tremendous potential as a photocatalysts for the MO degradation.

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