Untangling the Effect of Carbonaceous Materials on the Photoelectrochemical Performance of BaTaO<sub>2</sub>N
Mirabbos HojamberdievInstitut für Chemie, Technische Universität Berlin, Straße des 17. Juni 135, 10623 Berlin, GermanyRonald VargasEscuela de Bio y Nanotecnologías, Universidad Nacional de San Martín (UNSAM), Avenida Intendente Marino, Km 8,2, B7130IWA Chascomús, Provincia de Buenos Aires, ArgentinaLorean MadrizEscuela de Bio y Nanotecnologías, Universidad Nacional de San Martín (UNSAM), Avenida Intendente Marino, Km 8,2, B7130IWA Chascomús, Provincia de Buenos Aires, ArgentinaZukhra C. KadirovaUzbekistan–Japan Innovation Center of Youth, University Street 2B, 100095 Tashkent, UzbekistanKunio YubutaDepartment of Applied Quantum Physics and Nuclear Engineering, Kyushu University, Fukuoka 819-0395, JapanFuxiang ZhangState Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, iChEM, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, ChinaKatsuya TeshimaDepartment of Materials Chemistry, Shinshu University, 4-17-1 Wakasato, Nagano 380-8553, JapanMartin LerchInstitut für Chemie, Technische Universität Berlin, Straße des 17. Juni 135, 10623 Berlin, Germany
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Аннотация
, respectively. The observed trends in the dark for the oxygen reduction reaction (ORR) potential align with the increase in the photocurrent density, revealing a good correlation between opposite phenomena. Importantly, the enhancement observed implies an underlying accumulation phenomenon. The verification of this concept lies in the evidence provided by oxygen reduction and is in line with photoredox flux matching during photocatalysis. This research underscores the intricate interplay between carbonaceous materials and oxynitride photocatalysts, offering a strategic approach to enhancing various photocatalytic capabilities.
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