Synthesis, crystal structure and Hirshfeld surface of bis(acetato-κ <sup>2</sup> <i>O</i> , <i>O</i> ′)(2-benzyl-1 <i>H</i> -benzimidazole-κ <i>N</i> <sup>3</sup> )copper(II)
Gulnoza BoboyevaNational University of Uzbekistan named after Mirzo Ulugbek University Street 4 Tashkent 100174 UzbekistanGulbeka MamatovaNational University of Uzbekistan named after Mirzo Ulugbek University Street 4 Tashkent 100174 UzbekistanSardor MurodovNational University of Uzbekistan named after Mirzo Ulugbek University Street 4 Tashkent 100174 UzbekistanKomila GaniyevaBranch of D. I. Mendeleev University of Chemical Technology of Russia, 100142, Tashkent, Mirzo-Ulugbek District, TTZ-1, 47, UzbekistanK. K. TurgunovInstitute of the Chemistry of Plant Substances, Uzbekistan Academy of Sciences, Mirzo Ulugbek Str. 77, Tashkent 100170, UzbekistanB. TashkhodjaevInstitute of the Chemistry of Plant Substances, Uzbekistan Academy of Sciences, Mirzo Ulugbek Str. 77, Tashkent 100170, UzbekistanShahlo DaminovaNational University of Uzbekistan named after Mirzo Ulugbek University Street 4 Tashkent 100174 Uzbekistan
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Аннотация
The title copper(II) complex, [Cu(C 2 H 3 O 2 ) 2 (C 14 H 12 N 2 ) 2 ], was synthesized and structurally characterized. It crystallizes in the monoclinic space group P2 1 /n with one molecule per asymmetric unit. The Cu 2+ ion exhibits a distorted octahedral (4 + 2) coordination geometry. The crystal packing is consolidated by N—H...O hydrogen bonds and C—H...π interactions. Hirshfeld surface analysis indicates that H...H, H...C/C...H and O...H/H...O contacts are the major contributors to the crystal packing.
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