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Efficient extraction of lithium ions from brine: A sustainable approach

Nigora QutlimurotovaNational university of UzbekistanUmida AkhmedovaNational university of UzbekistanOydin TuyevaNational university of UzbekistanZukhra YakhshievaJizzakh State Pedagogical UniversityMansur AshirovKhorezm Ma’mun AcademyJamoliddin RazzokovInstitute of Fundamental and Applied Research, National Research University TIIAME
Results in Chemistryjournal2025en
ABI

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<title>Abstract</title> The production of lithium batteries is one of the fastest-growing industries globally, driving the demand for efficient lithium compound extraction techniques. The separation of lithium ions from magnesium poses a significant challenge due to their similar chemical properties. To address this, ion exchange sieves, sorbents, and electrosorbents are commonly employed. In this study, we developed an acetate-phosphate-cellulose sorbent by incorporating phosphoric acid into acetate cellulose. The sorbent demonstrated a static exchange capacity of 25.48 mg/g for lithium hydroxide and was effectively regenerated with 0.4 N HCl. Even after 10 reapplications, the sorption efficiency remained above 93%, showcasing the material's durability and reusability. The composition and structure of the sorbent were confirmed through SEM analysis, IR spectroscopy, and potentiometric titration, revealing a phosphoric acid residue trapping efficiency of 33%. This work presents a cost-effective, recyclable material with promising potential for industrial lithium recovery.

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