Обзорная статья

A comprehensive review on carbonylation reactions: catalysis by magnetic nanoparticle-supported transition metals

Irfan AhmadDepartment of Clinical Laboratory Sciences, College of Applied Medical Sciences, King Khalid University, Abha, Saudi ArabiaMunthar KedhimCollege of Pharmacy, The Islamic University, Najaf, IraqYashwantsinh JadejaMarwadi University Research Center, Department of Chemistry, Faculty of Science, Marwadi University, Rajkot 360003, Gujarat, IndiaGargi SangwanChitkara Centre for Research and Development, Chitkara University, Baddi, Himachal Pradesh, 174103, IndiaV KavithaDepartment of Chemistry, Sathyabama Institute of Science and Technology, Chennai, Tamil Nadu, IndiaAditya KashyapCentre for Research Impact & Outcome, Chitkara University Institute of Engineering and Technology, Chitkara University, Rajpura, 140401, Punjab, IndiaShirin ShomurotovaDepartment of Chemistry Teaching Methods, Tashkent State Pedagogical University named after Nizami, Bunyodkor Street 27, Tashkent, UzbekistanMosstafa KazemiYoung Researchers and Elite Club, Islamic Azad University, Tehran Branch, Tehran, IranRamin JavahershenasOrganic Development, Chemistry Faculty, Urmia University, Urmia, Iran

Nanoscale Advancesjournal2025en

ABI

Аннотация

Magnetic catalysts have become a crucial innovation in carbonylation reactions, providing a sustainable and highly efficient means of synthesizing compounds that contain carbonyl groups. This review article explores the diverse and significant role of magnetic catalysts in various carbonylation processes, emphasizing their essential contributions to improving reaction rates, selectivity, and recyclability of catalysts. The distinctive magnetic properties of these catalysts enable straightforward separation and recovery, a feature that significantly mitigates waste and reduces environmental impact. As a result, magnetic catalysts' environmental and economic advantages position them as key players in contemporary synthetic chemistry, driving the evolution of green chemistry practices. Particularly noteworthy is the combination of magnetic nanoparticles with transition metals, resulting in the development of robust catalytic systems that exploit the complementary effects of magnetism and catalysis. Recent advances have showcased the adaptability of magnetic nanoparticles supported by transition metal catalysts in various carbonylation reactions, including carbonylative coupling, alkoxy carbonylation, thio carbonylation, and amino carbonylation. This review meticulously examines the mechanistic aspects of how magnetic fields influenced catalytic performance between 2014 and the end of 2024.

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Темы

Carbon dioxide utilization in catalysis Chemical Synthesis and Reactions Asymmetric Hydrogenation and Catalysis

Идентификаторы

DOI: 10.1039/d5na00040h

Цитирования и источники

Цитирований: 0Использованных источников: 153

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