Hydrothermal Transformation of Organic Matter in the Case of Domanik Shale Deposits

The presence of source rock with a high concentration of kerogen is not a sufficient condition for petroleum formation, as maturation requires specific thermodynamic conditions. In this study, the artificial maturation of organic matter was investigated through hydrothermal treatment simulating the vaporization-condensation zones associated with in situ combustion and steam-assisted recovery processes. The experiments were conducted under an inert nitrogen atmosphere at 250-350 °C to reproduce oxygen-depleted thermal environments where hydrothermal reactions dominate. The results demonstrate that the bitumoid yield increases with temperature, reaching a maximum of 4.44 wt.% at 300 °C, followed by a decline at 350 °C due to secondary cracking. At the same time, gas generation increases significantly, with a more than five-fold rise in total gas yield between 250 and 350 °C. In parallel, the H/C atomic ratio of kerogen decreases from 1.17 in the initial sample to 0.52 at 350 °C, indicating progressive aromatization and advanced catagenetic transformation. These changes are accompanied by the conversion of high-molecular-weight kerogen into resins, asphaltenes, and subsequently lighter hydrocarbons. The study provides experimental evidence for the effectiveness of hydrothermal processes in inducing kerogen transformation under inert conditions, offering insights into the mechanisms governing artificial maturation in unconventional reservoirs.

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