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Ti<sub>3</sub>C<sub>2</sub> MXenes with Modified Surface for High-Performance Electromagnetic Absorption and Shielding in the X-Band

Meikang HanScience and Technology on Thermostructural Composite Materials Laboratory, Northwestern Polytechnical University, Xi’an, 710072, ChinaXiaowei YinScience and Technology on Thermostructural Composite Materials Laboratory, Northwestern Polytechnical University, Xi’an, 710072, ChinaHeng WuScience and Technology on Thermostructural Composite Materials Laboratory, Northwestern Polytechnical University, Xi’an, 710072, ChinaZexin HouScience and Technology on Thermostructural Composite Materials Laboratory, Northwestern Polytechnical University, Xi’an, 710072, ChinaChangqing SongScience and Technology on Thermostructural Composite Materials Laboratory, Northwestern Polytechnical University, Xi’an, 710072, ChinaXinliang LiScience and Technology on Thermostructural Composite Materials Laboratory, Northwestern Polytechnical University, Xi’an, 710072, ChinaLitong ZhangScience and Technology on Thermostructural Composite Materials Laboratory, Northwestern Polytechnical University, Xi’an, 710072, ChinaLaifei ChengScience and Technology on Thermostructural Composite Materials Laboratory, Northwestern Polytechnical University, Xi’an, 710072, China
2016en
ABI

Аннотация

Electromagnetic (EM) absorbing and shielding composites with tunable absorbing behaviors based on Ti3C2 MXenes are fabricated via HF etching and annealing treatment. Localized sandwich structure without sacrificing the original layered morphology is realized, which is responsible for the enhancement of EM absorbing capability in the X-band. The composite with 50 wt % annealed MXenes exhibits a minimum reflection loss of -48.4 dB at 11.6 GHz, because of the formation of TiO2 nanocrystals and amorphous carbon. Moreover, superior shielding effectiveness with high absorption effectiveness is achieved. The total and absorbing shielding effectiveness of Ti3C2 MXenes in a wax matrix with a thickness of only 1 mm reach values of 76.1 and 67.3 dB, while those of annealed Ti3C2 MXenes/wax composites are 32 and 24.2 dB, respectively. Considering the promising performance of Ti3C2 MXenes with the modified surface, this work is expected to open the door for the expanded applications of MXenes family in EM absorbing and shielding fields.

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