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Achieving Persistent Room Temperature Phosphorescence and Remarkable Mechanochromism from Pure Organic Luminogens

Yongyang GongShanghai Key Lab of Electrical Insulation and Thermal Aging School of Chemistry and Chemical Engineering Shanghai Jiao Tong University No. 800 Dongchuan Rd. Minhang District Shanghai 200240 ChinaGan ChenShanghai Key Lab of Electrical Insulation and Thermal Aging School of Chemistry and Chemical Engineering Shanghai Jiao Tong University No. 800 Dongchuan Rd. Minhang District Shanghai 200240 ChinaQian PengInstitute of Chemistry; Chinese Academy of Sciences; Zhongguancun North First Street 2 Haidian District Beijing 100190 ChinaWang Zhang YuanShanghai Key Lab of Electrical Insulation and Thermal Aging School of Chemistry and Chemical Engineering Shanghai Jiao Tong University No. 800 Dongchuan Rd. Minhang District Shanghai 200240 ChinaYujun XieInstitute of Chemistry Chinese Academy of Sciences Zhongguancun North First Street 2 Haidian District Beijing 100190 ChinaShuhong LiSchool of Science Beijing Technology and Business University No. 11/33 Fucheng Rd. Haidian District Beijing 100048 ChinaYongming ZhangShanghai Key Lab of Electrical Insulation and Thermal Aging School of Chemistry and Chemical Engineering Shanghai Jiao Tong University No. 800 Dongchuan Rd. Minhang District Shanghai 200240 ChinaBen Zhong TangDepartment of Chemistry The Hong Kong University of Science and Technology Clear Water Bay Kowloon Hong Kong China
2015en
ABI

Аннотация

Persistent room temperature phosphorescence (RTP) from pure organic luminogens can be rationally realized based on the crystallization-induced phosphorescence phenomenon and severe crystallization. A perfect crystal with dense molecular packing and effective inter­molecular interactions isolates the triplet excitons from quenching sites and significantly blocks the high-energy vibrational dissipation, thus yielding long-lasting RTP. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

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