Статья

Synthesis and Stability of Tagged UiO-66 Zr-MOFs

Mathivathani KandiahDepartment of Chemistry, University of Oslo, P.O. Box 1033, N-0315 Oslo, Norway,Merete Hellner NilsenDepartment of Chemistry, University of Oslo, P.O. Box 1033, N-0315 Oslo, Norway,Sandro UsseglioDepartment of Chemistry, University of Oslo, P.O. Box 1033, N-0315 Oslo, Norway,Søren JakobsenDepartment of Chemistry, University of Oslo, P.O. Box 1033, N-0315 Oslo, Norway,Unni OlsbyeDepartment of Chemistry, University of Oslo, P.O. Box 1033, N-0315 Oslo, Norway,Mats TilsetDepartment of Chemistry, University of Oslo, P.O. Box 1033, N-0315 Oslo, Norway,Cherif LarabiUniversité de Lyon, LCOMS, UMR 5265 C2P2 CPE-UCBL1-CNRS Bâtiment 308 ; 43 Boulevard du 11 Novembre 1918; F-69616, Villeurbanne, FranceElsje Alessandra QuadrelliUniversité de Lyon, LCOMS, UMR 5265 C2P2 CPE-UCBL1-CNRS Bâtiment 308 ; 43 Boulevard du 11 Novembre 1918; F-69616, Villeurbanne, FranceFrancesca BoninoDepartment of Chemistry IFM & NIS Centre of Excellence, University of Torino, Via Quarello 11, I-10125 Torino, ItalyKarl Petter LillerudDepartment of Chemistry, University of Oslo, P.O. Box 1033, N-0315 Oslo, Norway,

2010en

ABI

Аннотация

The development in the field MOF materials is moving from the discovery of new structures toward applications of the most promising materials. In most cases, specialized applications require incorporation of functional chemical groups. This work is a systematic investigation of the effect that simple substituents attached to the aromatic linker have on the stability and property to the parent MOF. A family of isoreticular MOFs, based on the UiO-66 structure was obtained from the three different linker ligands H2N−H2BDC, O2N−H2BDC, and Br−H2BDC. The physicochemical and chemical investigation of these materials demonstrate that this class of MOFs retains high thermal and chemical stabilities, even with functional groups present at the linker units. The results demonstrate the possibility of incorporating active functional groups into the UiO-66 structure almost without losing its exceptionally high thermal and chemical stability. It has been established that the functional groups, at least in the amino functionalized UiO-66 sample, are chemically available as evidenced by the H/D exchange experiment, making the tagged UiO series MOFs very interesting for further studies within the field of catalysis.

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Идентификаторы

DOI: 10.1021/cm102601v

Цитирования и источники

Цитирований: 3Использованных источников: 0

Показатели — AkademScholar