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Green synthesis of silver nanoparticles using <i>Carica Papaya</i> fruit extract under sunlight irradiation and their colorimetric detection of mercury ions

M. Lutfi FirdausGraduate School of Science Education, University of Bengkulu 38371, IndonesiaSeptika AndrianaGraduate School of Science Education, University of Bengkulu 38371, IndonesiaElvinawatiGraduate School of Science Education, University of Bengkulu 38371, IndonesiaWiwit AlwiGraduate School of Science Education, University of Bengkulu 38371, IndonesiaEko SwistoroGraduate School of Science Education, University of Bengkulu 38371, IndonesiaAceng RuyaniGraduate School of Science Education, University of Bengkulu 38371, IndonesiaAgus SundaryonoGraduate School of Science Education, University of Bengkulu 38371, Indonesia
2017en
ABI

Аннотация

We have successfully synthesized silver nanoparticles (AgNPs) by using aqueous extract of papaya (Carica papaya) fruit as bioreductant under sunlight irradiation without additional capping agent. Characterizations were done using UV-Visible spectrophotometry and Fourier Transform Infrared Spectroscopy (FTIR). The synthesized AgNPs have yellowish-brown color with surface plasmon resonance peak at 410 nm. Good selectivity of the AgNPs towards hazardous heavy metal of mercury ions in aqueous solution has been developed as a green environmental sensor. The presence of Hg(II) ions in the mixture changed the yellowish-brown color of AgNPs to colorless due to oxidation of Ag(O) in AgNPs to Ag(I) ions. Effect of samples matrix such as alkali metal, alkaline earth metal and transition metal ions were evaluated.

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