Rational Synthesis of Stable Channel-Like Cavities with Methane Gas Adsorption Properties: [{Cu2(pzdc)2(L)}n] (pzdc=pyrazine-2,3-dicarboxylate; L=a Pillar Ligand)
Mitsuru KondoDepartment of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Sakyoku, Kyoto 606–8501 (Japan),Takashi OkuboDepartment of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Minami-ohsawa Hachioji, Tokyo 192–0397 (Japan)Akiko AsamiDepartment of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Minami-ohsawa Hachioji, Tokyo 192–0397 (Japan)Shin‐ichiro NoroDepartment of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Minami-ohsawa Hachioji, Tokyo 192–0397 (Japan)Tomomichi YoshitomiDepartment of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Minami-ohsawa Hachioji, Tokyo 192–0397 (Japan)Susumu KitagawaDepartment of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Sakyoku, Kyoto 606–8501 (Japan),Tomohiko IshiiDepartment of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Minami-ohsawa Hachioji, Tokyo 192–0397 (Japan)Hiroyuki MatsuzakaDepartment of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Minami-ohsawa Hachioji, Tokyo 192–0397 (Japan)Kenji SekiEnergy Conversion and Storage Technology Applied Research Center, Research and Development Department, Osaka Gas Co., Ltd., Torishima, Konohana-ku, Osaka 554-0051 (Japan)
1999en
ABI
Аннотация
Stable tunable channels are formed by pillared-layer-type coordination networks [{Cu2(pzdc)2(L)}n] (pzdc = pyrazine-2,3-dicarboxylate; L = pyrazine, 4,4′-bipyridine, N-(4-pyridyl)isonicotinamide). Not only their channel sizes, shapes, and chemical environments are systematically built up by tuning the pillar ligands, but also the porosity is maintained in the absence of the included guest molecules. These compounds can adsorb methane, and the amount of gas adsorption is controllable by the type of pillar ligands.
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