Facile Access to Ring-Fused Aminals via Direct α-Amination of Secondary Amines with <i>ortho</i>-Aminobenzaldehydes. Synthesis of Vasicine, Deoxyvasicine, Deoxyvasicinone, Mackinazolinone and Ruteacarpine.
Matthew T. RichersDepartment of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, Piscataway, New Jersey 08854, USAIndubhusan DebDepartment of Chemistry & Chemical Biology, Rutgers The State University of New JerseyA. Yu. PlatonovaDepartment of Chemistry and Chemical Biology, Rutgers, The State University of New JerseyChen ZhangDepartment of Chemistry & Chemical Biology, Rutgers The State University of New JerseyDaniel SeidelDepartment of Chemistry & Chemical Biology, Rutgers The State University of New Jersey
2013en
ABI
Аннотация
-alkylation. This unique α-functionalization reaction proceeds without the involvement of transition metals or other additives. The resulting aminal products are precursors for various quinazolinone alkaloids and their analogues.
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