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Asernestioside C, a new minor saponin from the roots of Astragalus ernestii COMB.; First example of negative nuclear Overhauser effect in the saponins.

Hui Kang WangOsaka University, Osaka, JapanKan HeOsaka University, Osaka, JapanJi LiOsaka University, Osaka, JapanYasuhiro TezukaOsaka University, Osaka, JapanTohru KikuchiOsaka University, Osaka, JapanIsao KitagawaOsaka University, Osaka, Japan
1989en
ABI

Аннотация

A minor saponin, asernestioside C (1), was isolated from the roots of Astragalus ernestii COMB. (Leguminosae) and its structure was determined from the two-dimensional nuclear magnetic resonance spectra and nuclear Overhauser effect (NOE) difference spectra. In this case, negative NOE was observed between the 3-H and the anomeric proton of 3-O-sugar moiety and between the 24-H and the 26-H3. Examples of negative NOE were also found in some other saponins.

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