Clean and Efficient Synthesis Using Mechanochemistry: Coordination Polymers, Metal-Organic Frameworks and Metallodrugs
Tomislav FriščićDepartment of Chemistry, McGill University, 801 Sherbrooke St. W., H3A 0B8 Montréal, Quebéc, CanadaIván HalászDepartment of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102a, HR-10002 Zagreb, CroatiaVjekoslav ŠtrukilLaboratory for Physical-Organic Chemistry, Division of Organic Chemistry and Biochemistry, Rudjer Bošković Institute, 10002 Zagreb, CroatiaMirjana Eckert‐MaksićLaboratory for Physical-Organic Chemistry, Division of Organic Chemistry and Biochemistry, Rudjer Bošković Institute, 10002 Zagreb, CroatiaRobert E. DinnebierMax-Planck Institute for Solid State Research, Heisenbergstrasse 1, Stuttgart, D-70569, Germany
2012en
ABI
Аннотация
This review briefly discusses recent advances and future prospects in the mechanochemical synthesis of coordination compounds by ball milling and grinding, and highlights our contributions to the mechanosynthesis of porous metal-organic frameworks (MOFs) and zeolitic imidazolate frameworks (ZIFs), metal-organic pharmaceutical derivatives and metallodrugs using the recently developed mechanochemical methods of liquid-assisted grinding (LAG) and ion-and liquid-assisted grinding (ILAG). The role of mechanochemistry in the development of a solvent-free laboratory, cocrystal synthesis and new materials for luminescence and gas absorption is also highlighted. (
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