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The Current Status of MOF and COF Applications

Ralph FreundSolid State Chemistry University of Augsburg GermanyOrysia ZarembaBCMaterials, Basque Center for Materials UPV/EHU Science Park Leioa 48940 SpainGiel ArnautsCenter for Membrane Separations, Adsorption, Catalysis and Spectroscopy (cMACS) KU Leuven BelgiumRob AmelootCenter for Membrane Separations, Adsorption, Catalysis and Spectroscopy (cMACS) KU Leuven BelgiumGrigorii SkorupskiiDepartment of Chemistry Massachusetts Institute of Technology Cambridge USADinca, MirceaDepartment of Chemistry Massachusetts Institute of Technology Cambridge USAAnastasiya BavykinaKing Abdullah University of Science and Technology KAUST Catalysis Center (KCC) Advanced Catalytic Materials Saudi ArabiaJorge GascónKing Abdullah University of Science and Technology KAUST Catalysis Center (KCC) Advanced Catalytic Materials Saudi ArabiaAleksander EjsmontFaculty of Chemistry Adam Mickiewicz University in Poznan PolandJoanna GościańskaFaculty of Chemistry Adam Mickiewicz University in Poznan PolandMarkus J. KalmutzkiAnton Paar (Germany) GmbH Ostfildern GermanyUlrich LächeltDepartment of Pharmacy and Center for NanoScience (CeNS) LMU Munich GermanyEvelyn PloetzDepartment of Chemistry and Center for NanoScience (CeNS) LMU Munich GermanyChristian S. DiercksMaterials Sciences Division Lawrence Berkeley National Laboratory Kavli Energy NanoSciences Institute Berkeley CA 94720 USAStefan WuttkeBCMaterials, Basque Center for Materials UPV/EHU Science Park Leioa 48940 Spain
2021en
ABI

Аннотация

The amalgamation of different disciplines is at the heart of reticular chemistry and has broadened the boundaries of chemistry by opening up an infinite space of chemical composition, structure, and material properties. Reticular design has enabled the precise prediction of crystalline framework structures, tunability of chemical composition, incorporation of various functionalities onto the framework backbone, and as a consequence, fine-tuning of metal-organic framework (MOF) and covalent organic framework (COF) properties beyond that of any other material class. Leveraging the unique properties of reticular materials has resulted in significant advances from both a fundamental and an applied perspective. Here, we wish to review the milestones in MOF and COF research and give a critical view on progress in their real-world applications. Finally, we briefly discuss the major challenges in the field that need to be addressed to pave the way for industrial applications.

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