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Hollow semiconductor photocatalysts for solar energy conversion

Bin FangDepartment of Environmental Science, School of Chemistry and Materials Science, Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, Heilongjiang University, Harbin 150080, ChinaZipeng XingDepartment of Environmental Science, School of Chemistry and Materials Science, Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, Heilongjiang University, Harbin 150080, ChinaDandan SunDepartment of Environmental Science, School of Chemistry and Materials Science, Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, Heilongjiang University, Harbin 150080, ChinaZhenzi LiShandong Provincial Key Laboratory of Molecular Engineering, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, ChinaWei ZhouDepartment of Environmental Science, School of Chemistry and Materials Science, Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, Heilongjiang University, Harbin 150080, China
2021en
ABI

Аннотация

The development of high-efficient photocatalysts plays an important role in the sustainable utilization of solar energy. Hollow nanostructured photocatalysts are vital for solar light utilization and charge carrier separation in photocatalytic processes. Therefore, the construction of hollow semiconductor photocatalysts is a promising strategy for preparing novel high-efficient photocatalysts. This paper reviews common hollow semiconductor nanomaterials, such as oxides, sulfides, nitrides, C3N4, MOFs, and their composite photocatalysts. The characteristics of hollow-structure photocatalysts, the application of solar energy conversion, and their understanding of the photocatalytic mechanism are also reviewed. In addition, future challenges will be focused on designing and majorizing broadband response hollow-structure photocatalysts to further enhance solar energy conversion. Hollow semiconductor photocatalysts will have potential applications in the natural environment, and these synthesized strategies can also provide new possibilities for synthesizing other high-performance semiconductor photocatalysts.

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