Статья

Floatable S-scheme Bi2WO6/C3N4/carbon fiber cloth composite photocatalyst for efficient water decontamination

Mingjie CaiKey Laboratory of Health Risk Factors for Seafood of Zhejiang Province, National Engineering Research Center for Marine Aquaculture, College of Marine Science and Technology, Zhejiang Ocean University, Zhoushan 316022, Zhejiang, ChinaYanping LiuKey Laboratory of Health Risk Factors for Seafood of Zhejiang Province, National Engineering Research Center for Marine Aquaculture, College of Marine Science and Technology, Zhejiang Ocean University, Zhoushan 316022, Zhejiang, ChinaKexin DongKey Laboratory of Health Risk Factors for Seafood of Zhejiang Province, National Engineering Research Center for Marine Aquaculture, College of Marine Science and Technology, Zhejiang Ocean University, Zhoushan 316022, Zhejiang, ChinaXiaobo ChenDepartment of Chemistry, University of Missouri-Kansas City, MO 64110, USAShijie LiKey Laboratory of Health Risk Factors for Seafood of Zhejiang Province, National Engineering Research Center for Marine Aquaculture, College of Marine Science and Technology, Zhejiang Ocean University, Zhoushan 316022, Zhejiang, China

2023en

ABI

Аннотация

The development of easily recyclable and advanced photosystems is a promising strategy for achieving sustainable water decontamination in industrial applications. In this study, a flexible, floatable, and easily recyclable S-scheme photosystem of oxygen vacancy (OV)-rich Bi2WO6/C3N4/carbon fiber cloth (BWOV/CN/CF) was fabricated via sequential in situ growth of C3N4 and Bi2WO6 with oxygen vacancies on CF cloth. The integrated BWOV/CN/CF photosystem exhibited outstanding photocatalytic decontamination rates for TC (0.0353 min−1) and Cr(VI) (0.0187 min−1), significantly exceeding CN/CF by 0.5 and 30.2 folds, respectively. This appreciable improvement is derived from the unique hierarchical S-scheme heterostructure with OV, which enables the enhanced capability of BWOV/CN/CF in light use and powerful photocarrier detachment, as well as offering abundant active centers. Significantly, the BWOV/CN/CF cloth shows intriguing industrial application prospects owing to its high anti-interference properties, broad pH applicability, good durability, easy recycling and operation, and extensive adaptability for diverse contaminant purification. Furthermore, the photocatalytic TC decomposition process, by-product biotoxicity, and photocatalysis mechanism were systematically evaluated. The ingenious design of floatable cloth-shaped photosystems offers an effective strategy for environmental purification.

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Идентификаторы

DOI: 10.1016/s1872-2067(23)64496-1

Цитирования и источники

Цитирований: 8Использованных источников: 0

Показатели — AkademScholar