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Thermal and solute diffusion in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" altimg="si1.svg"> <mml:mrow> <mml:mi mathvariant="bold-italic">α</mml:mi> </mml:mrow> </mml:math> -Mg dendrite growth of Mg-5wt.%Zn alloy: A phase-field study

Weipeng ChenSchool of Materials Science and Engineering, Collaborative Innovation Center of Ministry of Education and Shanxi Province for High-performance Al/Mg Alloy Materials, North University of China, Taiyuan, 030051, ChinaHua HouSchool of Materials Science and Engineering, Collaborative Innovation Center of Ministry of Education and Shanxi Province for High-performance Al/Mg Alloy Materials, North University of China, Taiyuan, 030051, ChinaYuntao ZhangSchool of Materials Science and Engineering, Collaborative Innovation Center of Ministry of Education and Shanxi Province for High-performance Al/Mg Alloy Materials, North University of China, Taiyuan, 030051, ChinaWei LiuSchool of Materials Science and Engineering, Collaborative Innovation Center of Ministry of Education and Shanxi Province for High-performance Al/Mg Alloy Materials, North University of China, Taiyuan, 030051, ChinaYuhong ZhaoBeijing Advanced Innovation Center for Materials Genome Engineering, University of Science and Technology Beijing, Beijing, 100083, China
2023lv
ABI

Аннотация

Thermal and solute diffusion plays an important role in α-Mg dendrite growth, the diffusion mechanism of which is still unclear. Here, thermal and solute diffusion in α-Mg dendrite growth of Mg-5wt.%Zn alloy under non-isothermal solidification were studied using the phase-field method. Results show that solidification latent heat will be concentrated at the dendrite intersection, which makes thermal field distribution non-uniform, and it is similar to the profile formed by connecting primary dendrite tips. The increase in temperature will shorten primary dendrite arms, reduce side-branching development, increase dendrite tip temperature, and decrease dendrite tip concentration stability. Moreover, solidification latent heat will first diffuse to undercooled melt, then diffuse to other areas, finally, system temperature tends to be unified. The variation range of concentration difference is very small in the solidification process, and solute field distribution is uniform all the time. The local high-concentration areas will be formed after the superposition of the solute enrichment layer, and solute atoms will first diffuse to undercooled melt through the solid-liquid interface, and then concentrate between side-branching and dendrites.

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