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Recycling Mg(OH)<sub>2</sub>Nanoadsorbent during Treating the Low Concentration of Cr<sup>VI</sup>

Weizhen LiuState Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, ChinaFeng HuangYongjing WangTing ZouJinsheng ZhengZhang Lin
2011en
ABI

Аннотация

Investigations about how to recycle the deactivated nanomaterials are well-needed. This work was designed to explore the recycling strategy of Mg(OH)(2) nanoadsorbent during treating low concentration of Cr(VI) solution as an example. It was demonstrated that a reversible route between Cr-adsorbed nano-Mg(OH)(2) and Cr-desorbed bulk-MgCO(3) · 3H(2)O can be established by using CO(2) as a phase transformation medium. In each adsorption-desorption cycle, Cr(VI) solution with initial concentration of 10 mg · L(-1) could be enriched over 40 times. An aggregation-induced rapid phase transformation mechanism from nano-Mg(OH)(2) to bulk-MgCO(3) · 3H(2)O was discovered, which was one of the critical factors to ensure the disposing efficiency of this environmental-friendly Cr(VI) disposal system. A pilot-scale experiment was conducted with this strategy to deal with 50 L Cr(VI)-containing simulated industrial wastewater. The enrichment of Cr(VI) and the recycle of nano-Mg(OH)(2) can be successfully achieved simultaneously.

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