Low temperature fabrication of SnO2, ZnO and Zn2SnO4 nanostructures for the degradation of Rhodamine 6G: characterization
Аннотация
The SnO2, ZnO and Zn2SnO4 nanostructures (NSs) were prepared using sol-gel method and different techniques were used to investigate their physicochemical properties. The crystalline nature of the NSs was evaluated using X-ray diffractometer (XRD) technique and the calculated crystallite sizes are 24.68, 29.13 and 31.74 nm. To explore the surface properties, scanning electron microscope (SEM) was utilized and the particles were found to exhibit smooth surface with varied morphology. Energy dispersive X-ray (EDX) spectroscopy was used for the determination of purity and percentage composition of the NSs. The band gap energy was calculated from Tauc’s plot using diffuse reflectance spectroscopy (DRS). The Fourier transform infrared (FTIR) spectroscopy spotted the surface functional groups. As-synthesized nanostructures were applied as photocatalysts for the degradation of Rhodamine 6g (Rh-6G) by irradiating under simulated solar light. The percentage degradation and degradation rate constant was deduced by using a set of equations, which shows that the photocatalytic performance of Zn2SnO4 was significantly high than their counterparts.
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