Обзорная статья

A comprehensive review of template-assisted porous carbons: Modern preparation methods and advanced applications

Vladimir PavlenkoAl-Farabi Kazakh National University, 71 al-Farabi Ave., 050040 Almaty, KazakhstanS. Khosravi HInstitute for Chemistry and Technology of Materials, Graz University of Technology, Stremayrgasse 9, 8010 Graz, AustriaS. ŻółtowskaInstitute of Chemical Technology and Engineering, Faculty of Chemical Technology, Poznan University of Technology, Berdychowo 4, 60965 Poznan, PolandAderemi B. HarunaMolecular Sciences Institute, School of Chemistry, University of the Witwatersrand, Private Bag 3, PO Wits, Johannesburg 2050, South AfricaMuhammad ZahidDepartment of Chemistry, University of Agriculture Faisalabad, PakistanЗ. А. МансуровAl-Farabi Kazakh National University, 71 al-Farabi Ave., 050040 Almaty, KazakhstanZhazira SupiyevaAl-Farabi Kazakh National University, 71 al-Farabi Ave., 050040 Almaty, KazakhstanAhmed GalalChemistry Department, Faculty of Science, Cairo University, 12613 Giza, EgyptKenneth I. OzoemenaMolecular Sciences Institute, School of Chemistry, University of the Witwatersrand, Private Bag 3, PO Wits, Johannesburg 2050, South AfricaQamar AbbasInstitute for Chemistry and Technology of Materials, Graz University of Technology, Stremayrgasse 9, 8010 Graz, AustriaTeofil JesionowskiInstitute of Chemical Technology and Engineering, Faculty of Chemical Technology, Poznan University of Technology, Berdychowo 4, 60965 Poznan, Poland

2022en

ABI

Аннотация

Carbons with hierarchical pores in the range of few nanometers obtained via template-assisted methods offer a great control over structure and geometry of pores, keeping them uniformly distributed and better connected. Another advantage is the easy functionalization of templated porous carbons (TPCs) by various dopants, which makes them excellent materials for catalysis, energy storage and conversion, sensors and environmental applications. Herein, beyond zeolite-templated carbons, key methodologies based on the template material such as organic and metal oxides, silica, polymers, metal-organic framework (MOFs) and bio-originated materials used for the preparation of porous carbons possessing predetermined structure and composition, have been reviewed. The effects of precursor material on the textural and structural properties of TPCs have been described. In scope of applying novel methods such as evaporation induced self-assembling (EISA), the influence of different templates on the properties of resulting materials has been discussed. Further, advances on the template-induced synthesis of self-supporting metal-organic frameworks and their utilization as advanced templates have been described. Moreover, self-templates are especially emphasized, application of which in our opinion can provide a sustainable large-scale production of TPCs. The recent progress in the study of the diffusional processes, energy and biomedical applications as well as the confinement effects of different liquids and proteins within the porous matrices of template-derived carbons, have been reviewed.

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Идентификаторы

DOI: 10.1016/j.mser.2022.100682

Цитирования и источники

Цитирований: 2Использованных источников: 0

Показатели — AkademScholar