Understanding, quantifying, and controlling the molecular ordering of semiconducting polymers: from novices to experts and amorphous to perfect crystals
Zhengxing PengDepartment of Physics and Organic and Carbon Electronics Laboratories (ORaCEL), North Carolina State University, Raleigh, North Carolina 27695, USALong YeDepartment of Physics and Organic and Carbon Electronics Laboratories (ORaCEL), North Carolina State University, Raleigh, North Carolina 27695, USAHarald AdeDepartment of Physics and Organic and Carbon Electronics Laboratories (ORaCEL), North Carolina State University, Raleigh, North Carolina 27695, USA
2021en
ABI
Аннотация
) and thermal transitions. A small database is presented for 13 representative conjugated and insulating polymers ranging from amorphous to semi-paracrystalline. Finally, we outline the challenges to rationally design more perfect polymer crystals and propose a new molecular design approach that envisions conceptual molecular grafting that is akin to strained and unstrained hetero-epitaxy in classic (compound) semiconductors thin film growth.
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