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Evolution paths from gray to turquoise hydrogen via catalytic steam methane reforming: Current challenges and future developments

Samrand SaeidiBiotechnology Center, Silesian University of Technology, 8 Krzywousty St., 44-100 Gliwice, PolandAndrás SápiDepartment of Applied and Environmental Chemistry, Interdisciplinary Excellence Centre, University of Szeged, Rerrich Béla tér 1, Szeged 6720, HungaryAsif Hussain KhojaFossil Fuel Laboratory, Department of Thermal Energy Engineering, U.S.-Pakistan Centre for Advanced Studies in Energy (USPCAS-E), National University of Sciences & Technology (NUST), Sector H-12 Islamabad (44000), PakistanSara NajariDepartment of Applied and Environmental Chemistry, Interdisciplinary Excellence Centre, University of Szeged, Rerrich Béla tér 1, Szeged 6720, HungaryMariam AyeshaSchool of Chemical and Materials Engineering (SCME), National University of Sciences & Technology (NUST), Sector H-12 Islamabad (44000), PakistanZoltán KónyaDepartment of Applied and Environmental Chemistry, Interdisciplinary Excellence Centre, University of Szeged, Rerrich Béla tér 1, Szeged 6720, HungaryBernard Baffour Asare BediakoCenter for Renewable Carbon, University of Tennessee, Knoxville 37996, USAAdam TatarczukVolker HesselSchool of Chemical Engineering, The University of Adelaide, North Terrace Campus, Adelaide, 5005, AustraliaFrerich J. KeilInstitute of Chemical Reaction Engineering, Hamburg University of Technology, Hamburg D-21073, GermanyAlı́rio E. RodriguesLaboratory of Separation and Reaction Engineering – Laboratory of Catalysis and Materials (LSRE-LCM), Associate Laboratory LSRE-LCM, Faculdade de Engenharia, Universidade do Porto, Rua Dr. Roberto Frias, 4200-465, Porto, Portugal
2023en
ABI

Аннотация

Fossil fuel depletion, global warming, climate change, and steep hikes in the price of fuel are driving scientists to investigate commercial and environmentally friendly energy carriers like hydrogen. Steam methane reforming (SMR), a current commercial route for H2 production, has been considered the best remedy to fulfill the requirements. Despite the remarkable quantity of H2 produced by the SMR, this technology still faces major challenges such as catalyst deactivation due to the sintering of metal nanoparticles, coking, and generation of a large quantity of CO2. Firstly, the effects of catalyst types, kinetic models, and operating conditions on high-yield H2 production, the evolution path from gray to blue, via the conventional SMR are comprehensively reviewed. Secondly, exploiting intensified techniques such as membrane technology, sorption, fluidization, and chemical looping for SMR to blue H2 are discussed in detail. Further, a novel and sustainable path for the SMR process, hybridizing the use of novel materials and emerging technologies to produce turquoise H2, is proposed. Finally, the critical points for steam reforming process technology that can help leverage environmental, social, and governance (ESG) profiling have been discussed.

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