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Visible‐Light Responsive TiO<sub>2</sub>‐Based Materials for Efficient Solar Energy Utilization

Wei ZhangDepartment of Chemistry Laboratory of Advanced Materials Shanghai Key Lab of Molecular Catalysis and Innovative Materials iChEM and State Key Laboratory of Molecular Engineering of Polymers Fudan University Shanghai 200433 P. R. ChinaHaili HeDepartment of Chemistry Laboratory of Advanced Materials Shanghai Key Lab of Molecular Catalysis and Innovative Materials iChEM and State Key Laboratory of Molecular Engineering of Polymers Fudan University Shanghai 200433 P. R. ChinaHaoze LiDepartment of Chemistry Laboratory of Advanced Materials Shanghai Key Lab of Molecular Catalysis and Innovative Materials iChEM and State Key Laboratory of Molecular Engineering of Polymers Fudan University Shanghai 200433 P. R. ChinaLinlin DuanDepartment of Chemistry Laboratory of Advanced Materials Shanghai Key Lab of Molecular Catalysis and Innovative Materials iChEM and State Key Laboratory of Molecular Engineering of Polymers Fudan University Shanghai 200433 P. R. ChinaLianhai ZuDepartment of Chemistry Laboratory of Advanced Materials Shanghai Key Lab of Molecular Catalysis and Innovative Materials iChEM and State Key Laboratory of Molecular Engineering of Polymers Fudan University Shanghai 200433 P. R. ChinaYunpu ZhaiGreen Catalysis Center College of Chemistry Zhengzhou University Zhengzhou 450001 P. R. ChinaWei LiDepartment of Chemistry Laboratory of Advanced Materials Shanghai Key Lab of Molecular Catalysis and Innovative Materials iChEM and State Key Laboratory of Molecular Engineering of Polymers Fudan University Shanghai 200433 P. R. ChinaLianzhou WangNanomaterials Centre School of Chemical Engineering Australian Institute for Bioengineering and Nanotechnology The University of Queensland Brisbane QLD 4072 AustraliaHonggang FuKey Laboratory of Functional Inorganic Material Chemistry Ministry of Education of the People's Republic of China Heilongjiang University Harbin 150080 P. R. ChinaDongyuan ZhaoDepartment of Chemistry Laboratory of Advanced Materials Shanghai Key Lab of Molecular Catalysis and Innovative Materials iChEM and State Key Laboratory of Molecular Engineering of Polymers Fudan University Shanghai 200433 P. R. China
2020en
ABI

Аннотация

Abstract The photocatalytic properties of TiO 2 have aroused a broad range of research interest since 1972 due to its abundance, chemical stability, and easily available nature. To increase its overall activity, in the past few decades, much effort has been devoted to the fabrication of advanced TiO 2 ‐based photocatalysts with visible‐light response and these photocatalysts have shown great potential in the field of solar energy utilization. Here, recent progress in the investigation of visible‐light responsive TiO 2 ‐based materials are reviewed. Notably, the fabrication strategies and corresponding chemical/physical properties of visible‐light responsive TiO 2 ‐based materials are described in detail, with a focus on bandgap engineering and junction engineering from the perspective of light absorption, charge transfer and separation, and surface reactions. Their applications in solar‐fuel production, organic synthesis, bacterial disinfection, pollutant degradation and nitrogen fixation are also discussed. Moreover, the new trends and ongoing challenges in this field are proposed and highlighted.

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