New <i>N</i>‐allylated monomers in the synthesis of practical valuable high‐molecular‐weight compounds

Abstract Methods for the synthesis of N ‐allylated monomers of new structural types based on transformations of hydrazides of carboxylic acids and guanidine have been developed. A reactivity of N,N ‐diallyl‐ N ′‐acylhydrazines (DAH) and 2,2‐diallyl‐1,1,3,3‐tetraethylguanidiniumchloride (AGC) in reactions of free‐radical homo‐ and copolymerization with sulfur dioxide and vinyl monomers has been studied. The structure of the polymers obtained was identified by NMR 13 C. Investigations carried out showed DAH and AGC to copolymerize with vinyl monomers and sulphur dioxide, both double bonds participating with the formation of cis ‐, trans ‐stereoisomeric pyrrolidine structures in cyclolinear polymer chain. Kinetic regularities of the process and some properties of the copolymers have been investigated. Copyright © 2008 John Wiley &amp; Sons, Ltd.

Перевод пока недоступен