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Synthesis and luminescent properties of novel red-emitting M7Sn(PO4)6:Eu3+(M= Sr,Ba) phosphors

Guo FengNational Engineering Research Center for Domestic & Building Ceramics, Jingdezhen Ceramic Institute, Jingdezhen, ChinaWeihui JiangNational Engineering Research Center for Domestic & Building Ceramics, Jingdezhen Ceramic Institute, Jingdezhen, China + Department of Material Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen, China + Jiangxi Key Laboratory of Advanced MJianmin LiuNational Engineering Research Center for Domestic & Building Ceramics, Jingdezhen Ceramic Institute, Jingdezhen, ChinaCong LiNational Engineering Research Center for Domestic & Building Ceramics, Jingdezhen Ceramic Institute, Jingdezhen, ChinaQuan ZhangNational Engineering Research Center for Domestic & Building Ceramics, Jingdezhen Ceramic Institute, Jingdezhen, China
2018en
ABI

Аннотация

Novel Eu3+-activated M7Sn(PO4)6 (where M = Sr, Ba) red-emitting phosphors were synthesized via conventional solid-state reaction method at 1200 ?C for 2 h. The luminescence properties of the prepared samples and quenching concentration of Sr7-xSn(PO4)6 :xEu3+ and Ba7-xSn(PO4)6 :xEu3+ were investigated. These phosphors can be efficiently excited by UV (395 nm) and visible blue (465 nm) light nicely matching the output wavelengths of the near-UV LEDs and InGaN blue LED chips and emit the red light. The critical concentrations of the Eu3+ activator were found to be 0.175mol and 0.21mol per formula unit for Sr7-xSn(PO4)6 :xEu3+ and Ba7-xSn(PO4)6 :xEu3+, respectively. The M7-xSn(PO4)6 :xEu3+ (M = Sr, Ba) phosphor may be a good candidate for light-emitting diodes application.

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