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Structure, Properties and Applications of Two‐Dimensional Hexagonal Boron Nitride

Soumyabrata RoyDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAXiang ZhangDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAAnand B. PuthirathDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAMeiyazhagan AshokkumarDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAS. P. BhattacharyyaDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAMuhammad M. RahmanDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAGanguli BabuDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USASandhya SusarlaMaterials Science Division Lawrence Berkeley National Laboratory 1 Cyclotron Rd Berkeley CA 94720 USASreehari K. SajuDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAMai TranDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USALucas M. SassiDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAM. A. S. R. SaadiDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAJiawei LaiDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAOnur SahinDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USASeyed Mohammad SajadiDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USABhuvaneswari DharmarajanDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USADevashish SalpekarDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USANithya ChakingalDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAAbhijit BaburajDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAXinting ShuaiDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAAparna AdumbumkulathDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAKristen A. MillerDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAJessica GayleDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAAlec AjnsztajnDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAThibeorchews PrasankumarDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAVijay Vedhan Jayanthi HarikrishnanDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAVed OjhaDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAHarikishan KannanDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAAli KhaterDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAZhenwei ZhuDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USASathvik Ajay IyengarDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAPedro Alves da Silva AutretoCenter for Natural and Human Sciences Federal University of ABC (UFABC) Av. Dos Estados, 5001‐Bangú, Santo André – SP Santo André 09210–580 BrazilEliezer Fernando OliveiraApplied Physics Department State University of Campinas − UNICAMP Campinas São Paulo 13083–859 BrazilGuanhui GaoDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAA. Glen BirdwellCombat Capabilities Development Command U.S. Army Research Laboratory 2800 Powder Mill Road Adelphi MD 20783 USAMahesh R. NeupaneCombat Capabilities Development Command U.S. Army Research Laboratory 2800 Powder Mill Road Adelphi MD 20783 USATony IvanovCombat Capabilities Development Command U.S. Army Research Laboratory 2800 Powder Mill Road Adelphi MD 20783 USAJaime Taha‐TijerinaDepartment of Manufacturing and Industrial Engineering University of Texas Rio Grande Valley Brownsville TX 78520 USARam Manohar YadavDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USASivaram ArepalliDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USARóbert VajtaiDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USAPulickel M. AjayanDepartment of Materials Science and NanoEngineering Rice University 6100 Main St. Houston TX 77005 USA
2021en
ABI

Аннотация

Hexagonal boron nitride (h-BN) has emerged as a strong candidate for two-dimensional (2D) material owing to its exciting optoelectrical properties combined with mechanical robustness, thermal stability, and chemical inertness. Super-thin h-BN layers have gained significant attention from the scientific community for many applications, including nanoelectronics, photonics, biomedical, anti-corrosion, and catalysis, among others. This review provides a systematic elaboration of the structural, electrical, mechanical, optical, and thermal properties of h-BN followed by a comprehensive account of state-of-the-art synthesis strategies for 2D h-BN, including chemical exfoliation, chemical, and physical vapor deposition, and other methods that have been successfully developed in recent years. It further elaborates a wide variety of processing routes developed for doping, substitution, functionalization, and combination with other materials to form heterostructures. Based on the extraordinary properties and thermal-mechanical-chemical stability of 2D h-BN, various potential applications of these structures are described.

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