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Biofuel production, hydrogen production and water remediation by photocatalysis, biocatalysis and electrocatalysis

Ahmed I. OsmanSchool of Chemistry and Chemical Engineering, Queen’s University Belfast, Belfast, BT9 5AG, Northern Ireland, UKAhmed M. ElgarahyEgyptian Propylene and Polypropylene Company (EPPC), Port-Said, EgyptAbdelazeem S. EltaweilChemistry Department, Faculty of Science, Alexandria University, Alexandria, EgyptEman M. Abd El-MonaemChemistry Department, Faculty of Science, Alexandria University, Alexandria, EgyptHisham G. El-AqapaChemistry Department, Faculty of Science, Alexandria University, Alexandria, EgyptYuri ParkDepartment of Environmental Engineering, Seoul National University of Science and Technology, Seoul, 01811, South KoreaYuhoon HwangDepartment of Environmental Engineering, Seoul National University of Science and Technology, Seoul, 01811, South KoreaAli AyatiChemBio Cluster, ITMO University, Lomonosova Street 9, Saint Petersburg, Russia, 191002Mohamed FarghaliDepartment of Agricultural Engineering and Socio-Economics, Kobe University, Kobe, 657-8501, JapanIkko IharaDepartment of Agricultural Engineering and Socio-Economics, Kobe University, Kobe, 657-8501, JapanAla’a H. Al‐MuhtasebDepartment of Petroleum and Chemical Engineering, College of Engineering, Sultan Qaboos University, Muscat, OmanDavid W. RooneySchool of Chemistry and Chemical Engineering, Queen’s University Belfast, Belfast, BT9 5AG, Northern Ireland, UKPow‐Seng YapDepartment of Civil Engineering, Xi’an Jiaotong-Liverpool University, Suzhou, 215123, ChinaMika SillanpääDepartment of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600, Bangi, Selangor, Malaysia
2023en
ABI

Аннотация

Abstract The energy crisis and environmental pollution have recently fostered research on efficient methods such as environmental catalysis to produce biofuel and to clean water. Environmental catalysis refers to green catalysts used to breakdown pollutants or produce chemicals without generating undesirable by-products. For example, catalysts derived from waste or inexpensive materials are promising for the circular economy. Here we review environmental photocatalysis, biocatalysis, and electrocatalysis, with focus on catalyst synthesis, structure, and applications. Common catalysts include biomass-derived materials, metal–organic frameworks, non-noble metals nanoparticles, nanocomposites and enzymes. Structure characterization is done by Brunauer–Emmett–Teller isotherm, thermogravimetry, X-ray diffraction and photoelectron spectroscopy. We found that water pollutants can be degraded with an efficiency ranging from 71.7 to 100%, notably by heterogeneous Fenton catalysis. Photocatalysis produced dihydrogen (H 2 ) with generation rate higher than 100 μmol h −1 . Dihydrogen yields ranged from 27 to 88% by methane cracking. Biodiesel production reached 48.6 to 99%.

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