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Sustainable eco‐friendly sub‐micron <scp>NaCl</scp> crystal powder‐assisted method to synthesize <scp>SiO<sub>x</sub></scp>/C as anode materials originated from rice husk for lithium‐ion batteries

Se Hun LeeCenter for Applied Electromagnetic Research for Advanced Institute of Convergence Technology Seoul National University Gyeonggi‐do Republic of KoreaYoungseul ChoProgram in Nano Science and Technology, Graduate School of Convergence Science and Technology Seoul National University Suwon‐Si Republic of KoreaYoung Pyo JeonCenter for Applied Electromagnetic Research for Advanced Institute of Convergence Technology Seoul National University Gyeonggi‐do Republic of KoreaYujin ChangDepartment of Applied Bioengineering, Graduate School of Convergence Science and Technology Seoul National University Suwon‐Si Republic of KoreaKyu Sang LeeDepartment of Applied Bioengineering, Graduate School of Convergence Science and Technology Seoul National University Suwon‐Si Republic of KoreaDongpyo HongCenter for Applied Electromagnetic Research for Advanced Institute of Convergence Technology Seoul National University Gyeonggi‐do Republic of KoreaOk Sung JeonCenter for Applied Electromagnetic Research for Advanced Institute of Convergence Technology Seoul National University Gyeonggi‐do Republic of KoreaYongyeol ParkCenter for Applied Electromagnetic Research for Advanced Institute of Convergence Technology Seoul National University Gyeonggi‐do Republic of KoreaHyun Seo YangCenter for Applied Electromagnetic Research for Advanced Institute of Convergence Technology Seoul National University Gyeonggi‐do Republic of KoreaYoung Joon YooCenter for Applied Electromagnetic Research for Advanced Institute of Convergence Technology Seoul National University Gyeonggi‐do Republic of KoreaSang Yoon ParkCenter for Applied Electromagnetic Research for Advanced Institute of Convergence Technology Seoul National University Gyeonggi‐do Republic of KoreaYuanzhe PiaoDepartment of Applied Bioengineering, Graduate School of Convergence Science and Technology Seoul National University Suwon‐Si Republic of Korea
2023en
ABI

Аннотация

Abstract In the present study, we produced SiO x /C from rice husk by the NaCl sub‐micron crystal‐assisted synthesis method which can mitigate environmental degradation and hazards, simplify preparation, and improve electrochemical performance. During synthesis, NaCl induces catalytic graphitization, carbon activation, and amorphous silica formation. Moreover, it is only partially consumed and can be recrystallized and reused indefinitely. Our NaCl sub‐micron crystal powder‐assisted method created lithium‐ion batteries (LIBs) with rice husk‐derived SiO x /C anodes that exhibited a high initial charge/discharge capacity of 422.05/915.93 mAh∙g −1 at 0.05 A∙g −1 current density and stable cycling performance. In addition, the SiO x /C electrode produced by the NaCl micro‐crystal method had 333.96 mAh∙g −1 capacity at 0.05 A∙g −1 current density. By contrast, bare rice husk electrode exhibited a lower capacity of 333.96 mAh∙g −1 at the same condition. image

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