Spodium Bonds: Noncovalent Interactions Involving Group 12 Elements
Antonio BauzáDepartament de Química Universitat de les Illes Balears Crta de Valldemossa km 7.5 07122 Palma de Mallorca (Baleares SpainIbón AlkortaInstituto de Química Médica Juan de la Cierva, 3 28006- Madrid SpainJosé ElgueroInstituto de Química Médica Juan de la Cierva, 3 28006- Madrid SpainTiddo J. MooibroekVan't Hoff Institute for Molecular Sciences University of Amsterdam Science Park A, 904, E1.26 1098 XH Amsterdam The NetherlandsAntonio FronteraDepartament de Química Universitat de les Illes Balears Crta de Valldemossa km 7.5 07122 Palma de Mallorca (Baleares Spain
2020en
ABI
Аннотация
The term spodium (Sp) bond is proposed to refer to a net attractive interaction between any element of Group 12 and electron-rich atoms (Lewis bases or anions). These noncovalent interactions are markedly different from coordination bonds (antibonding Sp-ligand orbital involved). Evidence is provided for the existence of this interaction by calculations at the RI-MP2/aug-cc-pVTZ level of theory, atoms-in-molecules, and natural bond orbital analyses and by examining solid-state structures in the Cambridge Structure Database.
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