Статья

Osme Bond: Geometric and Energetic Features in the Adducts between OsO<sub>4</sub> and Lewis Bases

Miriam CalabreseNFMLab–Department of Chemistry Materials and Chemical Engineering “Giulio Natta” Politecnico di Milano Via L. Mancinelli 7 I-20131 Milan ItalyAndrea PizziNFMLab–Department of Chemistry Materials and Chemical Engineering “Giulio Natta” Politecnico di Milano Via L. Mancinelli 7 I-20131 Milan ItalyAndrea DaolioNFMLab–Department of Chemistry Materials and Chemical Engineering “Giulio Natta” Politecnico di Milano Via L. Mancinelli 7 I-20131 Milan ItalyRoberta BeccariaNFMLab–Department of Chemistry Materials and Chemical Engineering “Giulio Natta” Politecnico di Milano Via L. Mancinelli 7 I-20131 Milan ItalyCristina Lo IaconoNFMLab–Department of Chemistry Materials and Chemical Engineering “Giulio Natta” Politecnico di Milano Via L. Mancinelli 7 I-20131 Milan ItalySteve ScheinerDepartment of Chemistry and Biochemistry Utah State University Logan Utah 84322-0300 United StatesGiuseppe ResnatiNFMLab–Department of Chemistry Materials and Chemical Engineering “Giulio Natta” Politecnico di Milano Via L. Mancinelli 7 I-20131 Milan Italy

2024en

ABI

Аннотация

Abstract Adducts between OsO 4 and Lewis bases exert a role in important oxidation processes such as epoxidation and dihydroxylation. It has been shown that the attractive interaction driving the formation of these adducts is a σ‐hole bond involving the metal as the electrophilic species; the term Osme Bond (OmB) was proposed for designating it. Here some new adducts between OsO 4 and various bases have been characterized through single crystal x‐ray diffraction (XRD) and computational studies (density functional theory, DFT), confirming the existence of a robust correlation between σ‐hole interaction energy and deformation of the tetrahedral geometry of OsO 4 . Also, some adducts formed by RuO 4 with nucleophiles were investigated computationally.

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Идентификаторы

DOI: 10.1002/chem.202304240

Цитирования и источники

Цитирований: 2Использованных источников: 0

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