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Biopolymer‐Based Flame Retardants and Flame‐Retardant Materials

Ying‐Jun XuInstitute of Functional Textiles and Advanced Materials, College of Textiles & Clothing, National Engineering Research Center for Advanced Fire‐Safety Materials D&A (Shandong), State Key Laboratory of Bio‐fibers and Eco‐textiles Qingdao University Qingdao 266071 ChinaKai ZhangInstitute of Functional Textiles and Advanced Materials, College of Textiles & Clothing, National Engineering Research Center for Advanced Fire‐Safety Materials D&A (Shandong), State Key Laboratory of Bio‐fibers and Eco‐textiles Qingdao University Qingdao 266071 ChinaJirong WangInstitute of Functional Textiles and Advanced Materials, College of Textiles & Clothing, National Engineering Research Center for Advanced Fire‐Safety Materials D&A (Shandong), State Key Laboratory of Bio‐fibers and Eco‐textiles Qingdao University Qingdao 266071 ChinaYu‐Zhong WangCollaborative Innovation Center for Eco‐Friendly and Fire‐Safety Polymeric Materials (MoE) National Engineering Laboratory of Eco‐Friendly Polymeric Materials (Sichuan) State Key Laboratory of Polymer Materials Engineering, College of Chemistry Sichuan University Chengdu 610064 China
2025en
ABI

Аннотация

Polymeric materials featuring excellent flame retardancy are essential for applications requiring high levels of fire safety, while those based on biopolymers are highly favored due to their eco-friendly nature, sustainable characteristics, and abundant availability. This review first outlines the pyrolysis behaviors of biopolymers, with particular emphasis on naturally occurring ones derived from non-food sources such as cellulose, chitin/chitosan, alginate, and lignin. Then, the strategies for chemical modifications of biopolymers for flame-retardant purposes through covalent, ionic, and coordination bonds are presented and compared. The emphasis is placed on advanced methods for introducing biopolymer-based flame retardants into polymeric matrices and fabricating biopolymer-based flame-retardant materials. Finally, the challenges for sustaining the current momentum in the utilization of biopolymers for flame-retardant purposes are further discussed.

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