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Experimental Analysis of Reaction Heat of CO2 Absorption of Phase Change Absorber AEP-DPA at Low Partial Pressure

Shijian LuChina Carbon Neutrality Institute, China University of Mining and Technology, Xuzhou 221008, ChinaFei YangChina Carbon Neutrality Institute, China University of Mining and Technology, Xuzhou 221008, ChinaJuanjuan ZhangChina Carbon Neutrality Institute, China University of Mining and Technology, Xuzhou 221008, ChinaNing WangChina Carbon Neutrality Institute, China University of Mining and Technology, Xuzhou 221008, ChinaLing LiuChina Carbon Neutrality Institute, China University of Mining and Technology, Xuzhou 221008, ChinaGuo‐Jun KangChina Carbon Neutrality Institute, China University of Mining and Technology, Xuzhou 221008, ChinaDongya ZhaoNew Energy College, China University of Petroleum (East China), Qingdao 266580, ChinaXulin YuSinopec Petroleum Engineering Corporation, Dongying 257061, ChinaQingfang LiSinopec Petroleum Engineering Corporation, Dongying 257061, China
2023en
ABI

Аннотация

The reaction heat of CO2 absorption by organic amines is directly related to the regenerative heat consumption of absorbers. Therefore, it is necessary to study and determine the heat of absorption reaction and heat of regeneration reaction of CO2 capture solvent before its industrial validation and application. According to the law of thermodynamics, a computer model of the heat of absorption reaction and desorption reaction is established and verified. The heat of reaction of the AEP-DPA phase transition absorption system was studied under different ratios, absorption temperatures, reaction concentrations and reaction pressures. The heat of reaction increases with concentration and decreases with pressure. The reaction heat of the AEP-DPA phase transition absorption system and MEA were compared. The optimum reaction conditions were as follows: AEP-DPA ratio 6:4, absorption temperature 40 °C. The reduction rate of absorption heat and regenerative heat of the AEP-DPA phase change absorption system is more than 35% and 31%, respectively.

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