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Constructing magnetic molecular solids by employing three-atom ligands as bridges

Xin‐Yi WangBeijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, ChinaZhe‐Ming WangBeijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, ChinaSong GaoBeijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
2007en
ABI

Аннотация

The combination of some three-atom bridges with paramagnetic 3d transition metal ions results in the systematic isolation of molecular magnetic materials, ranging from single-molecule and single-chain magnets to layered weak ferromagnets and three-dimensional porous magnets. The design strategy and role of secondary components, such as co-ligands, templates and other mixed short ligands are discussed.

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