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MFU‐4 – A Metal‐Organic Framework for Highly Effective H<sub>2</sub>/D<sub>2</sub> Separation

Julia TeufelMax Planck Institute for Intelligent Systems, Heisenbergstr. 3, 70569 Stuttgart, GermanyHyunchul OhMax Planck Institute for Intelligent Systems, Heisenbergstr. 3, 70569 Stuttgart, GermanyMichael HirscherMax Planck Institute for Intelligent Systems, Heisenbergstr. 3, 70569 Stuttgart, GermanyMohammad WahiduzzamanJacobs University, School of Engineering and Science, Campus Ring 1, 28759 Bremen, GermanyLyuben ZhechkovJacobs University, School of Engineering and Science, Campus Ring 1, 28759 Bremen, GermanyAgnieszka KucJacobs University, School of Engineering and Science, Campus Ring 1, 28759 Bremen, GermanyThomas HeineJacobs University, School of Engineering and Science, Campus Ring 1, 28759 Bremen, GermanyDmytro DenysenkoAugsburg University, Institute of Physics, Universitätsstr. 1, 86159 Augsburg, GermanyDirk VolkmerAugsburg University, Institute of Physics, Universitätsstr. 1, 86159 Augsburg, Germany
2012en
ABI

Аннотация

The metal-organic framework, MFU-4, possessing small cavities and apertures, is exploited for quantum sieving of hydrogen isotopes. Quantum mechanically, a molecule confined in a small cavity shows an increase in effective size depending on the particle mass, which leads to a faster deuterium adsorption from a H2/D2 isotope mixture. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

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