Energy transfer in Ce, Nd, and Yb co-doped YAG phosphors
Аннотация
YAG-Ce, Nd, and Yb phosphors with a triple-doped system are prepared by conventional solid-state reaction method. The fluorescence emission and excitation spectra are measured and analyzed. The influences of Yb 3+ doping concentration on the emission of Yb 3+ and Nd 3+ in YAG-Ce, Nd, and Yb are studied. The fluorescence decay spectra, lifetime, and energy transfer efficiency of Ce 3+ in different host materials of YAG-Ce and Yb, and YAG-Ce, Nd, and Yb are also compared. Furthermore, the trends of fluorescence decay spectra and the lifetimes of Nd 3+ and Yb 3+ in YAG-Ce, Nd, and Yb with the increase of Yb 3+ concentration are discussed. Results indicate that YAG-Ce, Nd, and Yb are good candidates for downconverting phosphor, with energy transfer efficiency reaching as high as 82.8%.
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