Oxidation of Water under Visible‐Light Irradiation over Modified BaTaO<sub>2</sub>N Photocatalysts Promoted by Tungsten Species
Kazuhiko MaedaDepartment of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1-NE-2 Ookayama, Meguro-ku, Tokyo 152-8550, Japan. [email protected]Daling LuCenter for Advanced Materials Analysis, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8550 (Japan)Kazunari DomenDepartment of Chemical System Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
2013en
ABI
Аннотация
Water splitting: In heterogeneous photocatalysis, it has been believed that doping transition-metal cations having partly filled d orbitals into semiconductor photocatalysts results in a significant drop in photocatalytic activity. Nevertheless, it was found that the activity for the water oxidation of BaTaO2N could be improved by seven times upon modification by pentavalent W species (see picture).
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