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Recent Advances in C–H Functionalization Using Electrochemical Transition Metal Catalysis

Cong MaState Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, ChinaPing FangState Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, ChinaTian‐Sheng MeiState Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China
2018en
ABI

Аннотация

Electrochemical transition metal catalysis is a powerful strategy for organic synthesis because it obviates the use of stoichiometric chemical oxidants and reductants. C–H bond functionalization offers a variety of useful conversions of simple and ubiquitous organic molecules into diverse functional groups in a single synthetic operation. This review summarizes recent progress in merging electrochemistry with transition metal-catalyzed C–H functionalization, specifically C–C, C–X (halogen), C–O, C–P, and C–N bond formation.

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