Ordered Mesoporous Polymers and Homologous Carbon Frameworks: Amphiphilic Surfactant Templating and Direct Transformation
Yu MengDepartment of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, PR ChinaDong GuDepartment of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China,Fuqiang ZhangDepartment of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China,Yifeng ShiDepartment of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China,Haifeng YangDepartment of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China,Zheng LiDepartment of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China,Chengzhong YuDepartment of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China,Bo TuDepartment of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China,Dongyuan ZhaoDepartment of Chemistry, Molecular Catalysis and Innovative Materials Lab, Fudan University, Shanghai 200433, P.R. China, Fax: (+86) 21-6564-1740
2005en
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Аннотация
Ultrahigh stability (>1400 °C) is found for the highly ordered mesoporous polymers and carbon frameworks synthesized from polymerization of phenol and formaldehyde around triblock copolymer templates. Calcination and carbonization lead to removal of the templates and formation of hexagonal and cubic carbon mesostructures with large uniform pores and surface areas (see schematic diagram).
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