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Novel V<sub>2</sub>O<sub>5</sub>/BiVO<sub>4</sub>/TiO<sub>2</sub> Nanocomposites with High Visible-Light-Induced Photocatalytic Activity for the Degradation of Toluene

Juanjuan SunState Key Laboratory of Fine Chemical, Key Laboratory of Industrial Ecology and Environmental Engineering (MOE), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, ChinaXinyong LiCentre for Energy (M473), The University of Western Australia, 35 Stirling Highway, Crawley, Washington 6009, AustraliaQidong ZhaoState Key Laboratory of Fine Chemical, Key Laboratory of Industrial Ecology and Environmental Engineering (MOE), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, ChinaJun KeState Key Laboratory of Fine Chemical, Key Laboratory of Industrial Ecology and Environmental Engineering (MOE), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, ChinaDongke ZhangCentre for Energy (M473), The University of Western Australia, 35 Stirling Highway, Crawley, Washington 6009, Australia
2014en
ABI

Аннотация

In an effort to develop nanostructured photocatalysts to achieve high performance in heterogeneous photocatalysis, a novel composite V2O5/BiVO4/TiO2 photocatalyst was successfully synthesized by using a sequentially hydrothermal and adhering method. The structural and optical properties of the as-prepared samples were comparatively characterized. The formed ternary nanojunctions were composed of TiO2 nanobelts and V2O5/BiVO4 nanorods which were self-assembled by smaller V2O5 and BiVO4 nanoparticles. Compared to pure TiO2 nanobelts and V2O5/BiVO4 nanorods, the V2O5/BiVO4/TiO2 composite exhibited higher photocatalytic activity in decomposition of gaseous toluene under visible light irradiation (λ > 400 nm). Electron spin resonance examination confirmed that the photoinduced active species (•OH and O2•–) were involved in the photocatalytic degradation of toluene. A detailed mechanism accounting for the enhanced photocatalytic activity of the V2O5/BiVO4/TiO2 nanocomposite was proposed in terms of the energy band structures of the components. The rationally designed ternary nanojunctions could effectively enhance the photocatalytic performance by increasing photoinduced charge carriers through the charges separation across their multiple interfaces.

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Идентификаторы

DOI
10.1021/jp5013076

Цитирования и источники

Цитирований: 2Использованных источников: 0
Показатели — AkademScholar