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Comparative study of photocatalytic activity of metals- and non-metals doped ZnO and TiO2 nanocatalysts for advanced photocatalysis

Hamad AlMohamadiSustainability Research Center, Islamic University of Madinah, Madinah, Saudi Arabia;Sameer A. AwadDepartment of Medical Laboratories Techniques, Al-Maarif University College, Ramadi, Iraq;Ashwani Kumar SharmaDepartment of Applied Sciences, Chandigarh Engineering College, Chandigarh Group of Colleges, Jhanjeri, Mohali 140307, Punjab, India;Normurоt FayzullaevDepartment of Polymer Chemistry and Chemical Technology, University Samarkand State University, Samarkand, 140101, Uzbekistan;Arístides Távara-AponteDepartamento Académico de Física, Universidad Nacional de Trujillo, Trujillo, Perú;Lincoln Chiguala-ContrerasUniversidad Nacional Agraria de la Selva, Tingo Maria, Perú;Abdelfattah AmariDepartment of Chemical Engineering, College of Engineering, King Khalid University, Abha 61411, Kingdom of Saudi Arabia;Carlos Rodriguez‐BenitesUniversidad de Ciencias y Artes de América Latina, Av. La Molina 3755, Lima, 15026, Perú;Mohamed A. TahoonChemistry Department, Faculty of Science, Mansoura University, Mansoura 35516, EgyptHossein EsmaeiliDepartment of Chemical Engineering, Bushehr, Branch, Islamic Azad University, Bushehr, Iran
Preprints.orgrepository2024en
ABI

Аннотация

This review article provides useful information on TiO2 and ZnO photocatalysts and their derivatives in removing organic contaminants such as different types of dyes, hydrocarbons, pesticides, etc. Also, the reaction mechanism of TiO2 and ZnO photocatalysts and their derivatives was investigated. In addition, the impact of adding metallic (e.g., Ag, Co, Pt, Pd, Cu, Au, Ni) and non-metallic (e.g., C, N, O, S) dopants to their structure on the photodegradation efficiency of organic compounds was thoroughly studied. Moreover, advantages and disadvantages of various synthesis procedures of ZnO and TiO2 nanocatalysts were discussed and compared. Furthermore, the impact of photocatalyst dosage, photocatalyst structure, contaminant concentration, pH, light intensity and wavelength, temperature and reaction time on the photodegradation efficiency was studied. According to previous studies, adding metallic and non-metallic dopants to the TiO2 and ZnO structure led to a remarkable enhance in their stability and reusability. Besides, doped TiO2 and ZnO demonstrated remarkable photocatalytic efficiencies in eliminating various types of organic contaminants.

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