Статья

Boosting the interfacial superionic conduction of halide solid electrolytes for all-solid-state batteries

Hiram KwakDepartment of Chemical and Biomolecular Engineering, Yonsei University, Seoul, 03722, South KoreaJae‐Seung KimDepartment of Chemical and Biomolecular Engineering, Yonsei University, Seoul, 03722, South KoreaDaseul HanDepartment of Energy and Materials Engineering, Dongguk University, Seoul, 04620, South KoreaJong Seok KimDepartment of Chemical and Biomolecular Engineering, Yonsei University, Seoul, 03722, South KoreaJuhyoun ParkDepartment of Chemical and Biomolecular Engineering, Yonsei University, Seoul, 03722, South KoreaGihan KwonNational Synchrotron Light Source II, Brookhaven National Laboratory, Upton, NY, 11973, USASeong‐Min BakDepartment of Materials Science and Engineering, Yonsei University, 03722, Seoul, South KoreaUn-Seon HeoDepartment of Energy and Materials Engineering, Dongguk University, Seoul, 04620, South KoreaChanghyun ParkSchool of Energy and Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 44919, South KoreaHyun‐Wook LeeSchool of Energy and Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 44919, South KoreaKyung‐Wan NamDepartment of Energy and Materials Engineering, Dongguk University, Seoul, 04620, South Korea. [email protected]Dong‐Hwa SeoSchool of Energy and Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 44919, South Korea. [email protected]Yoon Seok JungDepartment of Chemical and Biomolecular Engineering, Yonsei University, Seoul, 03722, South Korea. [email protected]

2023en

ABI

Аннотация

Abstract Designing highly conductive and (electro)chemical stable inorganic solid electrolytes using cost-effective materials is crucial for developing all-solid-state batteries. Here, we report halide nanocomposite solid electrolytes (HNSEs) ZrO 2 (-ACl)-A 2 ZrCl 6 (A = Li or Na) that demonstrate improved ionic conductivities at 30 °C, from 0.40 to 1.3 mS cm −1 and from 0.011 to 0.11 mS cm −1 for Li + and Na + , respectively, compared to A 2 ZrCl 6 , and improved compatibility with sulfide solid electrolytes. The mechanochemical method employing Li 2 O for the HNSEs synthesis enables the formation of nanostructured networks that promote interfacial superionic conduction. Via density functional theory calculations combined with synchrotron X-ray and 6 Li nuclear magnetic resonance measurements and analyses, we demonstrate that interfacial oxygen-substituted compounds are responsible for the boosted interfacial conduction mechanism. Compared to state-of-the-art Li 2 ZrCl 6 , the fluorinated ZrO 2 −2Li 2 ZrCl 5 F HNSE shows improved high-voltage stability and interfacial compatibility with Li 6 PS 5 Cl and layered lithium transition metal oxide-based positive electrodes without detrimentally affecting Li + conductivity. We also report the assembly and testing of a Li-In||LiNi 0.88 Co 0.11 Mn 0.01 O 2 all-solid-state lab-scale cell operating at 30 °C and 70 MPa and capable of delivering a specific discharge of 115 mAh g −1 after almost 2000 cycles at 400 mA g −1 .

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Идентификаторы

DOI: 10.1038/s41467-023-38037-z

Цитирования и источники

Цитирований: 2Использованных источников: 0

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