2D Porous Organic Templates via Cocrystallization of Melamine with Disulfonic Acids: Adsorption of Various Alcohols in SCSC Mode
Hyejin OhDepartment of Chemistry, Pusan National University, Busan 46241, Republic of KoreaDongwon KimCenter for Catalytic Hydrocarbon Functionalizations, Institute for Basic Science (IBS), Daejeon 34141, Republic of KoreaDongwook KimCenter for Catalytic Hydrocarbon Functionalizations, Institute for Basic Science (IBS), Daejeon 34141, Republic of KoreaIn‐Hyeok ParkDepartment of Chemistry, Pusan National University, Busan 46241, Republic of KoreaOk‐Sang JungDepartment of Chemistry, Pusan National University, Busan 46241, Republic of Korea
2020en
ABI
Аннотация
Cocrystallization of melamine with organic sulfonic acids (1,5-naphthalenedisulfonic acid and 4,4′-biphenyldisulfonic acid) gives rise to 2D porous organic frameworks. Each 2D framework has a different channel size according to the length of the organic sulfonic acids. The adsorption of various liquid alcohols (1-butanol, 1-hexanol, 1-octanol, 1-decanol, 1-dodecanol, tert-butanol, and 2-ethyl-1-hexanol) into the channels in the single-crystal to single-crystal (SCSC) mode was effective for each channel. The tailor-made metal-free organic pores presented herein can be useful components of a practical template for a 3D structure determination of various liquid alcohols.
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