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Enhanced visible light photocatalytic efficiency of La-doped ZnO nanofibers via electrospinning-calcination technology

Shaoju JianFujian Key Laboratory of Eco-Industrial Green Technology, College of Ecology and Resources Engineering, Wuyi University, Wuyishan, 354300, ChinaZhiwei TianJiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing, 210037, ChinaJiapeng HuFujian Key Laboratory of Eco-Industrial Green Technology, College of Ecology and Resources Engineering, Wuyi University, Wuyishan, 354300, ChinaKaiyin ZhangCollege of Mechanical and Electrical Engineering, Wuyi University, Wuyishan, 354300, ChinaZhang LinMedia Lab, Massachusetts Institute of Technology, Cambridge, MA, 02139, USAGaigai DuanFujian Key Laboratory of Eco-Industrial Green Technology, College of Ecology and Resources Engineering, Wuyi University, Wuyishan, 354300, ChinaWeisen YangFujian Key Laboratory of Eco-Industrial Green Technology, College of Ecology and Resources Engineering, Wuyi University, Wuyishan, 354300, ChinaShaohua JiangFujian Key Laboratory of Eco-Industrial Green Technology, College of Ecology and Resources Engineering, Wuyi University, Wuyishan, 354300, China
2021en
ABI

Аннотация

A series of La-doped ZnO (La/ZnO) nanofibers were prepared by electrospinning-calcination technology and characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), ultraviolet–visible (UV–Vis) absorption spectroscopy and specific surface area analysis. The effect of numerous operational parameters involving calcination temperature, La doping amount, La-doped ZnO concentration and initial Rhodamine B (Rh B) concentration on photocatalytic efficiency of the composite has been analyzed by using Rh B for degradation under the illumination of visible light. Under optimum conditions, ZnO doped with 1.5 ​at.% La achieved 94.31% Rh B degradation after 510 ​min of visible light illumination. The kinetic data of La/ZnO catalyst for Rh B photodegradation fitted the Langmuir-Hinshelwood first-order (LHFO) kinetic model well.

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