Статья

Multiple Function Hyperbranched Polysiloxane Nanoclusters for Controlling a Cross-Linking Structure to Convert Soy Meal into a Strong, Tough, and Multifunctional Adhesive

Jiawei ShaoMOE Key Laboratory of Wood Material Science and Application & Beijing Key Laboratory of Wood Science and Engineering, Beijing Forestry University, Beijing 100083, ChinaXinyi LiMOE Key Laboratory of Wood Material Science and Application & Beijing Key Laboratory of Wood Science and Engineering, Beijing Forestry University, Beijing 100083, ChinaTao LiuCollege of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha, Hunan 410004, ChinaShiqing ChenMOE Key Laboratory of Wood Material Science and Application & Beijing Key Laboratory of Wood Science and Engineering, Beijing Forestry University, Beijing 100083, ChinaShanshan GongMOE Key Laboratory of Wood Material Science and Application & Beijing Key Laboratory of Wood Science and Engineering, Beijing Forestry University, Beijing 100083, ChinaJinfeng CaoMOE Key Laboratory of Wood Material Science and Application & Beijing Key Laboratory of Wood Science and Engineering, Beijing Forestry University, Beijing 100083, ChinaWenrui ZhouMOE Key Laboratory of Wood Material Science and Application & Beijing Key Laboratory of Wood Science and Engineering, Beijing Forestry University, Beijing 100083, ChinaCheng LiCollege of Forestry, Henan Agricultural University, Zhengzhou 450002, ChinaJianzhang LiMOE Key Laboratory of Wood Material Science and Application & Beijing Key Laboratory of Wood Science and Engineering, Beijing Forestry University, Beijing 100083, China

2024en

ABI

Аннотация

From an environmentally sustainable perspective, soybean meal (SM) adhesive presents an ideal alternative to petrochemical-based adhesives. Generally, strength and toughness are mutually exclusive for an adhesive. Hence, the creation of protein-based adhesives with high water-resistant strength of bonding, remarkable toughness, and multifunctionality remains a notable challenge. This study reports a dual hyperbranched siloxane nanocluster cross-linking strategy for creating SM-based adhesives with superior performance. In detail, synthesized hyperbranched epoxy siloxane nanocluster (ESN) and hyperbranched phenylboronic acid siloxane nanocluster (BPA@SN) were introduced into the SM matrix to establish a targeted cross-linking network between epoxy groups and protein chains as well as phenylboronic acid and polysaccharides. Meanwhile, the flexible Si–O segments within the hyperbranched siloxane facilitated energy dissipation, significantly boosting the adhesive toughness. After cross-linking modification, SM/ESN/BPA@SN-1 adhesive demonstrated outstanding dry bonding strength (2.04 ± 0.18 MPa), water-resistant bonding strength (1.12 ± 0.06 MPa), and toughness (18.5 ± 4.02 kJ/m3). Moreover, the adhesive exhibited distinctly improved resistance to mold, thermal stability, and flame retardancy. Therefore, this new strategy of using functional hyperbranched siloxane nanoclusters and SM to design strong, tough, and multifunctional green and sustainable wood-based biomass adhesives provides new ideas for achieving green development.

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Идентификаторы

DOI: 10.1021/acssuschemeng.3c06212

Цитирования и источники

Цитирований: 4Использованных источников: 0

Показатели — AkademScholar