Macrophyllols A and B, Two Unusual Novel Sesquiterpene and Monoterpene Dimers from the Bark of <i>Inula </i><i>m</i><i>acrophylla</i>
Bao‐Ning SuFaculty of Pharmaceutical Sciences, University of Tokushima, Shomachi 1-78, Tokushima 770-8505, Japan, Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Yamashiro-cho, Tokushima 770-8514, Japan, Faculty of Pharmaceutical Sciences, Kyoto University, Yoshida Sakyoku, Kyoto 606-8501, Japan, Faculty of Integrated Arts and Sciences, University of Tokushima, Jyosunjima, Tokushima 770, Japan, and Academy of Sciences Uzbekistan Institute of Botany, F. Khodzhaev, St. 32, 700143 Tashkent, UzbekistanYoshihisa TakaishiFaculty of Pharmaceutical Sciences, University of Tokushima, Shomachi 1-78, Tokushima 770-8505, Japan, Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Yamashiro-cho, Tokushima 770-8514, Japan, Faculty of Pharmaceutical Sciences, Kyoto University, Yoshida Sakyoku, Kyoto 606-8501, Japan, Faculty of Integrated Arts and Sciences, University of Tokushima, Jyosunjima, Tokushima 770, Japan, and Academy of Sciences Uzbekistan Institute of Botany, F. Khodzhaev, St. 32, 700143 Tashkent, UzbekistanMotoo ToriFaculty of Pharmaceutical Sciences, University of Tokushima, Shomachi 1-78, Tokushima 770-8505, Japan, Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Yamashiro-cho, Tokushima 770-8514, Japan, Faculty of Pharmaceutical Sciences, Kyoto University, Yoshida Sakyoku, Kyoto 606-8501, Japan, Faculty of Integrated Arts and Sciences, University of Tokushima, Jyosunjima, Tokushima 770, Japan, and Academy of Sciences Uzbekistan Institute of Botany, F. Khodzhaev, St. 32, 700143 Tashkent, UzbekistanShigeru TakaokaFaculty of Pharmaceutical Sciences, University of Tokushima, Shomachi 1-78, Tokushima 770-8505, Japan, Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Yamashiro-cho, Tokushima 770-8514, Japan, Faculty of Pharmaceutical Sciences, Kyoto University, Yoshida Sakyoku, Kyoto 606-8501, Japan, Faculty of Integrated Arts and Sciences, University of Tokushima, Jyosunjima, Tokushima 770, Japan, and Academy of Sciences Uzbekistan Institute of Botany, F. Khodzhaev, St. 32, 700143 Tashkent, UzbekistanGisho HondaFaculty of Pharmaceutical Sciences, University of Tokushima, Shomachi 1-78, Tokushima 770-8505, Japan, Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Yamashiro-cho, Tokushima 770-8514, Japan, Faculty of Pharmaceutical Sciences, Kyoto University, Yoshida Sakyoku, Kyoto 606-8501, Japan, Faculty of Integrated Arts and Sciences, University of Tokushima, Jyosunjima, Tokushima 770, Japan, and Academy of Sciences Uzbekistan Institute of Botany, F. Khodzhaev, St. 32, 700143 Tashkent, UzbekistanMichiho ItoFaculty of Pharmaceutical Sciences, University of Tokushima, Shomachi 1-78, Tokushima 770-8505, Japan, Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Yamashiro-cho, Tokushima 770-8514, Japan, Faculty of Pharmaceutical Sciences, Kyoto University, Yoshida Sakyoku, Kyoto 606-8501, Japan, Faculty of Integrated Arts and Sciences, University of Tokushima, Jyosunjima, Tokushima 770, Japan, and Academy of Sciences Uzbekistan Institute of Botany, F. Khodzhaev, St. 32, 700143 Tashkent, UzbekistanYoshio TakedaFaculty of Pharmaceutical Sciences, University of Tokushima, Shomachi 1-78, Tokushima 770-8505, Japan, Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Yamashiro-cho, Tokushima 770-8514, Japan, Faculty of Pharmaceutical Sciences, Kyoto University, Yoshida Sakyoku, Kyoto 606-8501, Japan, Faculty of Integrated Arts and Sciences, University of Tokushima, Jyosunjima, Tokushima 770, Japan, and Academy of Sciences Uzbekistan Institute of Botany, F. Khodzhaev, St. 32, 700143 Tashkent, UzbekistanOlimjon K. KodzhimatovFaculty of Pharmaceutical Sciences, University of Tokushima, Shomachi 1-78, Tokushima 770-8505, Japan, Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Yamashiro-cho, Tokushima 770-8514, Japan, Faculty of Pharmaceutical Sciences, Kyoto University, Yoshida Sakyoku, Kyoto 606-8501, Japan, Faculty of Integrated Arts and Sciences, University of Tokushima, Jyosunjima, Tokushima 770, Japan, and Academy of Sciences Uzbekistan Institute of Botany, F. Khodzhaev, St. 32, 700143 Tashkent, UzbekistanOzodbek AshurmetovFaculty of Pharmaceutical Sciences, University of Tokushima, Shomachi 1-78, Tokushima 770-8505, Japan, Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Yamashiro-cho, Tokushima 770-8514, Japan, Faculty of Pharmaceutical Sciences, Kyoto University, Yoshida Sakyoku, Kyoto 606-8501, Japan, Faculty of Integrated Arts and Sciences, University of Tokushima, Jyosunjima, Tokushima 770, Japan, and Academy of Sciences Uzbekistan Institute of Botany, F. Khodzhaev, St. 32, 700143 Tashkent, Uzbekistan
2000en
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Аннотация
[structure: see text] Two novel sesquiterpene and monoterpene dimers, macrophyllols A (1) and B (2), were isolated from the bark of Inula macrophylla. Their structures were determined on the basis of spectral evidence (especially HREIMS and 2D NMR) as well as chemical transformation. The structure of macrophyllol A (1) was confirmed by X-ray analysis. The possible biosynthetic pathways of macrophyllols A (1) and B (2) are discussed.
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