Pd‐Catalyzed Vinylation of Aryl Halides with Inexpensive Organosilicon Reagents Under Mild Conditions
Chu‐Ting YangInstitute of Nuclear Physics and Chemistry China Academy of Engineering Physics Mianyang 621900 P. R. ChinaJun HanInstitute of Nuclear Physics and Chemistry China Academy of Engineering Physics Mianyang 621900 P. R. ChinaJun LiuInstitute of Nuclear Physics and Chemistry China Academy of Engineering Physics Mianyang 621900 P. R. ChinaYi LiInstitute of Nuclear Physics and Chemistry China Academy of Engineering Physics Mianyang 621900 P. R. ChinaFan ZhangInstitute of Nuclear Physics and Chemistry China Academy of Engineering Physics Mianyang 621900 P. R. ChinaHaizhu YuDepartment of Chemistry and Center for Atomic Engineering of, Advanced Materials Anhui University Hefei 230026 P. R. ChinaSheng HuInstitute of Nuclear Physics and Chemistry China Academy of Engineering Physics Mianyang 621900 P. R. ChinaXiaolin WangInstitute of Nuclear Physics and Chemistry China Academy of Engineering Physics Mianyang 621900 P. R. China
2018en
ABI
Аннотация
Pd-catalyzed Hiyama vinylation reaction of non-activated aryl chlorides and bromides under mild conditions was developed. The use of efficient vinyl donors and electron-rich sterically hindered phosphine ligands was critical for the success of the reaction. The products of this transformation can be used for Am/Cm separation, an important challenge in nuclear fuel reprocessing. The substituent effect on Am/Cm separating selectivity was also achieved, which could contribute to the development of new chromatographic materials for the separation of Am and Cm.
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