Copper‐Catalyzed Sonogashira Reaction in Water
Yujia LiuEcole Nationale Supérieure de Chimie de Montpellier Institut Charles Gerhardt, CNRS, UMR 5253, AM2N 8 rue de l'Ecole Normale 34296 Montpellier Cedex 05 FranceVincent BlanchardEcole Nationale Supérieure de Chimie de Montpellier Institut Charles Gerhardt, CNRS, UMR 5253, AM2N 8 rue de l'Ecole Normale 34296 Montpellier Cedex 05 FranceGrégory DanounEcole Nationale Supérieure de Chimie de Montpellier Institut Charles Gerhardt, CNRS, UMR 5253, AM2N 8 rue de l'Ecole Normale 34296 Montpellier Cedex 05 FranceZhaoyang ZhangState Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University Chengdu 610500, P. R. ChinaAnis TliliEcole Nationale Supérieure de Chimie de Montpellier Institut Charles Gerhardt, CNRS, UMR 5253, AM2N 8 rue de l'Ecole Normale 34296 Montpellier Cedex 05 FranceWenlong ZhangState Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University Chengdu 610500, P. R. ChinaFlorian MonnierEcole Nationale Supérieure de Chimie de Montpellier Institut Charles Gerhardt, CNRS, UMR 5253, AM2N 8 rue de l'Ecole Normale 34296 Montpellier Cedex 05 FranceArie van der LeeInstitut Européen des Membranes, ENSCM Université de Montpellier, CNRS UMR 5635 34095 MONTPELLIER Cedex 5Jincheng MaoState Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University Chengdu 610500, P. R. ChinaMarc TailleferEcole Nationale Supérieure de Chimie de Montpellier Institut Charles Gerhardt, CNRS, UMR 5253, AM2N 8 rue de l'Ecole Normale 34296 Montpellier Cedex 05 France
2017en
ABI
Аннотация
Abstract Copper‐catalyzed Sonogashira reaction has been realized under biphasic conditions (water / organic substrates) allowing decreasing the copper loading up to 0.02–0.2 mol %. A potential intermediate species of the reaction, corresponding to a copper cluster linked with acetylide moiety, has been identified.
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